119971-63-0Relevant articles and documents
Novel Rearrangement of 5,6-Disubstituted Bicyclooctan-2-ones with AlCl3. Application to Total Synthesis of (+/-)-5-Oxosilphiperfol-6-ene and (+/-)-Silphiperfol-6-ene
Kakiuchi, Kiyomi,Ue, Masaki,Tsukahara, Hiroshi,Shimizu, Toshihiro,Miyao, Tomoya,et al.
, p. 3707 - 3712 (2007/10/02)
The acid-catalyzed rearrangement of bi- and tricyclic cyclobutyl ketones 8-20 having a bicyclooctan-2-one moiety with AlCl3 was studied to elucidate the scope and limitations of the novel rearrangement by which the tricyclic ketone 1 gave the angul