119987-22-3Relevant academic research and scientific papers
NOVEL APPROACH TO SEVEN-MEMBERED RINGS BY THE INTRAMOLECULAR TANDEM CYCLOPROPANATION/COPE REARRANGEMENT SEQUENCE
Davies, Huw M. L.,Oldenburg, C. E. Michael,McAfee, Melinda J.,Nordahl, J. Greg,Henretta, John P.,Romines, Karen R.
, p. 975 - 978 (1988)
The intramolecular tandem cyclopropanation/Cope rearrangement sequence between rhodium(II) acetate stabilized vivylcarbenoids and dienes is a feasible method for the stereospecific synthesis of fused seven-membered rings.
Stereoselective Synthesis of Seven-Membered Carbocycles by a Tandem Cyclopropanation/Cope Rearrangement between Rhodium(II)-Stabilized Vinylcarbenoids and Dienes
Davies, Huw M. L.,Clark, T. Jeffrey,Smith, H. David
, p. 3817 - 3824 (2007/10/02)
Rhodium(II)-catalyzed decomposition of vinyldiazomethanes in the presence of dienes generated 1,4-cycloheptadienes by a tandem cyclopropanation/Cope rearrangement.Excellent stereocontrol of up to three stereogenic centers in the cycloheptadienes was achie
