1199940-66-3Relevant academic research and scientific papers
Palladium-catalyzed formation of secondary and tertiary amines from aryl dihalides with air-stable ferrocenyl tri- and diphosphines: Synthesis and X-ray structure of efficient catalysts beyond [PdCl2(DPPF)]
Mom, Sophal,Platon, Mélanie,Cattey, Hélène,Spencer, Howard J.,Low, Paul J.,Hierso, Jean-Cyrille
, p. 10 - 14 (2014)
Robust, air-stable tridentate and bidentate ferrocenylphosphines 1,2-bis(diphenylphosphino)-1′-(diisopropylphosphino)-4-tert- butylferrocene, L5, and 1,1′-bis(diisopropylphosphino)-3,3′- bis(tert-butyl)ferrocene, L9, combined with 1 mol% of [PdCl(η3- C3H5)]2 led to two new catalytic systems which allow the coupling of aniline derivatives with mono- and dihaloarenes to form functionalized diarylamines and triarylamines. The excellent selectivity of the reactions avoids the deleterious dehalogenation of the substrates and products. The X-ray structure characterization of the related complex [PdCl 2(L9)] is reported in which ligand L9 in its meso form is significantly distorted.
DYE COMPOUND AND DYE-SENSITIZED SOLAR CELL
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Page/Page column 14, (2010/04/23)
A dye compound is described, which is expressed by formula (I): wherein A1, A2 and A3 each independently represent a substituted or unsubstituted 1,4-phenylene or 2,5-thiophene group, and B1 and B2 each independently represent a substituted or unsubstituted aryl group. The dye compound is suitably used as a dye sensitizer in a dye sensitized solar cell (DSSC).
Triaryl linked donor acceptor dyads for high-performance dye-sensitized solar cells
Chang, Yuan Jay,Chow, Tahsin J.
experimental part, p. 9626 - 9632 (2009/12/28)
The effect of changing substituents of organic dyes for their performance on dye-sensitized solar cells (DSSCs) is examined. These dyes consist of an aromatic amine donor group, a cyanoacrylic acid acceptor group, and a triaryl spacer group, while they ar
