1200119-13-6

Basic information

• Product Name: 3,5-di-O-benzyl-2-deoxy-α-D-ribofuranosyl azide
• CAS NO: 1200119-13-6
• Molecular Weight: 339.394
• Mol File: 1200119-13-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,5-di-O-benzyl-2-deoxy-α-D-ribofuranosyl azide(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-di-O-benzyl-2-deoxy-α-D-ribofuranosyl azide(1200119-13-6)
• EPA Substance Registry System: 3,5-di-O-benzyl-2-deoxy-α-D-ribofuranosyl azide(1200119-13-6)

Safety Data

• Hazardous Substances Data: 1200119-13-6(Hazardous Substances Data)

Upstream product

• 6160-50-5 3,5-di-O-benzyl-2-deoxy-D-ribofuranose 
• 6160-49-2 1-O-acetyl-3,5-di-O-benzyl-2-deoxy-D-erythro-pentofuranose 
• 4648-54-8 trimethylsilylazide 

Relevant articles and documents

Stereoselective construction of 1β-azido- And 1β-cyano-2-deoxyribose derivatives

A new method has been developed for the β-selective introduction of azido and cyano groups at the anomeric position of 2-deoxyribose derivatives. This method proceeds via the formation of a collidinium salt intermediate and allows for the stereoselective construction of 1β-azido- and 1β-cyano-2-deoxy-D-ribose derivatives. 2-Deoxy-D-ribose compounds bearing an acetoxy or tert-butoxycarbonyloxy group at their anomeric position performed well as starting materials for the formation of the corresponding 1β-azide and 1β-cyanide derivatives, respectively. 1H NMR studies of the salt intermediates revealed that the nucleophilic substitution reaction of the salt intermediates proceeded in a SN2-fashion.