1200124-03-3

Basic information

• Product Name: 2-(2,6-dichloro-4-methylphenyl)pyrimidine
• Synonyms: 2-(2,6-dichloro-4-methylphenyl)pyrimidine
• CAS NO: 1200124-03-3
• Molecular Weight: 204.659
• Mol File: 1200124-03-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2-(2,6-dichloro-4-methylphenyl)pyrimidine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2,6-dichloro-4-methylphenyl)pyrimidine(1200124-03-3)
• EPA Substance Registry System: 2-(2,6-dichloro-4-methylphenyl)pyrimidine(1200124-03-3)

Safety Data

• Hazardous Substances Data: 1200124-03-3(Hazardous Substances Data)

Upstream product

• 77232-13-4 2-p-tolyl-pyrimidine 
• 5720-05-8 4-methylphenylboronic acid 

Relevant articles and documents

Salen-based hypercrosslinked polymer-supported Pd as an efficient and recyclable catalyst for C-H halogenation

In this work, we report the first use of a salen-based hypercrosslinked polymer-supported Pd catalyst to carry out C-H halogenation. This catalyst can effectively catalyze C-H bromination and chlorination even better than its homogeneous counterpart Pd(OAc)2. It also showed excellent reusability without loss of catalytic activity for ten cycles. A broad substrate scope was explored and moderate to excellent yields were obtained.

Copper-catalyzed aromatic C-H bond halogenation with lithium halides under aerobic conditions

A concise and practical Cu-catalyzed protocol for the preparation of chloro- and bromoarenes via C-H bond activation has been developed. The advantages of this strategy are the employment of cheap Cu(NO3) 2·3H2O, LiX and O2, and its compatibility with both electron-donating and electron-withdrawing substituents on aryl rings.