120020-03-3

Basic information

• Product Name: 3-Benzyloxy-2-methyl-2-{[1-phenyl-meth-(E)-ylidene]-amino}-propionic acid methyl ester
• Synonyms: 3-Benzyloxy-2-methyl-2-{[1-phenyl-meth-(E)-ylidene]-amino}-propionic acid methyl ester
• CAS NO: 120020-03-3
• Molecular Weight: 311.381
• Mol File: 120020-03-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-Benzyloxy-2-methyl-2-{[1-phenyl-meth-(E)-ylidene]-amino}-propionic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Benzyloxy-2-methyl-2-{[1-phenyl-meth-(E)-ylidene]-amino}-propionic acid methyl ester(120020-03-3)
• EPA Substance Registry System: 3-Benzyloxy-2-methyl-2-{[1-phenyl-meth-(E)-ylidene]-amino}-propionic acid methyl ester(120020-03-3)

Safety Data

• Hazardous Substances Data: 120020-03-3(Hazardous Substances Data)

Upstream product

• 3587-60-8 Benzyloxymethyl chloride 
• 53933-42-9 2-(benzylidene-amino)-propionic acid methyl ester 

Relevant articles and documents

SOLID-LIQUID PHASE TRANSFER CATALYTIC SYNTHESIS OF α-AMINO ACID VIA ALKYLATION AND NUCLEOPHILIC ADDITION OF BENZALDEHYDE IMINES

A short, mild and efficient synthetic route of α-amino acid via alkylation, Michael addition and carbonyl addition as well as cycloaddition of aldimines derived from glycine and alanine esters with benzaldehyde under solid-liquid phase transfer catalytic condition has been studied.The key to solid-liquid phase transfer catalyzed reactions is the selection of a base for the various reactants.The yield is dependent on the base used.The results obtained using KOH, K2CO3 and Na2CO3 are discussed.The kinetics of solid-liquid PTC benzylation has been investigated and we propose a possible mechanism of solid-liquid PTC as an interface auto-catalytic procedure.The details of some syntheses of α-amino acids are presented.