1200441-82-2Relevant academic research and scientific papers
A general organocatalyzed Michael-Michael cascade reaction generates functionalized cyclohexenes
McGarraugh, Patrick G.,Jones, Joshua H.,Brenner-Moyer, Stacey E.
, p. 6309 - 6319 (2011)
Although β-dicarbonyl compounds are regularly employed as Michael donors, intermediates arising from the Michael addition of unsaturated β-ketoesters to α,β-unsaturated aldehydes are susceptible to multiple subsequent reaction pathways. We designed cyclic
A new organocatalyzed Michael-Michael cascade reaction generates highly substituted fused carbocycles
McGarraugh, Patrick G.,Brenner, Stacey E.
supporting information; experimental part, p. 5654 - 5657 (2010/02/28)
[Chemical Equation Presented] While β-ketoesters are useful Michael donors, they were previously ineffective in Michael-Michael cascade reactions using αβ-unsaturated aldehydes in conjunction with diphenylprolinol silyl ether organocatalysts. However, thr
