1200657-22-2Relevant academic research and scientific papers
Copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents
Millet, Renaud,Bernardez, Tania,Palais, La?titia,Alexakis, Alexandre
scheme or table, p. 3474 - 3477 (2009/09/28)
The desymmetrization of oxabenzonorbornadienes with aluminum reagents and SimplePhos as chiral ligand is described. The corresponding homoallylic alcohols are obtained in high yield, diastereoselectivity, and enantiomeric excess. Furthermore the first ant
Copper-catalyzed asymmetric ring-opening reaction of oxabenzonorbornadienes with Grignard and aluminum reagents
Millet, Renauds,Gremaud, Ludovic,Bernardez, Tania,Palais, Laetitia,Alexakis, Alexandre
experimental part, p. 2101 - 2112 (2009/12/31)
A highly enantioselective method for the copper-catalyzed desymmetrization of oxabenzonorbornadienes with aluminum reagents and SimplePhos as chiral ligand has been developed. The same reaction with Grignard reagents is also reported. A wide range of alky
