1200697-08-0

Basic information

• Product Name: 1-(hex-1-yn-1-yl)-1-methoxycyclohexane
• Synonyms: 1-(hex-1-yn-1-yl)-1-methoxycyclohexane
• CAS NO: 1200697-08-0
• Molecular Weight: 194.317
• Mol File: 1200697-08-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(hex-1-yn-1-yl)-1-methoxycyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(hex-1-yn-1-yl)-1-methoxycyclohexane(1200697-08-0)
• EPA Substance Registry System: 1-(hex-1-yn-1-yl)-1-methoxycyclohexane(1200697-08-0)

Safety Data

• Hazardous Substances Data: 1200697-08-0(Hazardous Substances Data)

Upstream product

• 15332-33-9 1-(hex-1-ynyl)cyclohexanol 
• 74-88-4 methyl iodide 
• 108-94-1 cyclohexanone 
• 693-02-7 hex-1-yne 

Downstream Products

• 75031-51-5 (1-cyclohexylidenehex-1-en-2-yl)benzene 
• 20023-45-4 hex-1-enylidenecyclohexane 

Relevant articles and documents

Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols

Herein we disclose an iron-catalyzed cross-coupling reaction of propargyl ethers with Grignard reagents. The reaction was demonstrated to be stereospecific and allows for a facile preparation of optically active allenes via efficient chirality transfer. Various tri- and tetrasubstituted fluoroalkyl allenes can be obtained in good to excellent yields. In addition, an iron-catalyzed cross-coupling of Grignard reagents with α-alkynyl oxetanes and tetrahydrofurans is disclosed herein, which constitutes a straightforward approach towards fully substituted β- or γ-allenols, respectively.