1200806-97-8

Basic information

• Product Name: 4-cyclohex-1-en-1-yl-1-(methylsulfonyl)-1H-1,2,3-triazole
• Synonyms: 4-cyclohex-1-en-1-yl-1-(methylsulfonyl)-1H-1,2,3-triazole
• CAS NO: 1200806-97-8
• Molecular Weight: 227.287
• Mol File: 1200806-97-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4-cyclohex-1-en-1-yl-1-(methylsulfonyl)-1H-1,2,3-triazole(CAS DataBase Reference)
• NIST Chemistry Reference: 4-cyclohex-1-en-1-yl-1-(methylsulfonyl)-1H-1,2,3-triazole(1200806-97-8)
• EPA Substance Registry System: 4-cyclohex-1-en-1-yl-1-(methylsulfonyl)-1H-1,2,3-triazole(1200806-97-8)

Safety Data

• Hazardous Substances Data: 1200806-97-8(Hazardous Substances Data)

Upstream product

• 28075-50-5 cyclohex-1-en-1-yl trifluoromethane sulfonate 
• 931-49-7 1-ethenylcyclohexene 
• 624-90-8 Methanesulfonyl azide 

Downstream Products

• 1200806-85-4 (1S,2R)-(+)-1-cyclohex-1-en-1-yl-2-phenylcyclopropanecarbaldehyde 
• 1608118-42-8 C₁₂H₂₀N₂O₃S 
• 1427205-76-2 (Z)-N-(5-(cyclohex-1-en-1-yl)-3-(methylsulfonyl)thiazol-2(3H)-ylidene)benzamide 

Relevant articles and documents

Direct production of enaminones from terminal alkynes via rhodium-catalyzed reaction of formamides with N-sulfonyl-1,2,3-triazoles

A rhodium-catalyzed reaction of formamides with N-sulfonyl-1,2,3-triazoles is developed to formulate a new one-pot procedure for the direct synthesis of α-amino enaminones from terminal alkynes.

Transannulation of 1-sulfonyl-1,2,3-triazoles with heterocumulenes

Readily available 1-mesyl-1,2,3-triazoles are efficiently converted into a variety of imidazolones and thiazoles by Rh(II)-catalyzed denitrogenative reactions with isocyanates and isothiocyanates, respectively. The proposed triazole-diazoimine equilibrium results in the formation of highly reactive azavinyl metal-carbenes, which react with heterocumulenes causing an apparent swap of 1,2,3-triazole core for another heterocycle.