120086-00-2

Upstream product

• 109-97-7 pyrrole 
• 17610-00-3 3,5-Di-tert-butylbenzaldehyde 
• 120085-99-6 2,9‐bis(4-formylphenyl)‐1,10‐phenanthroline 
• 135061-82-4 4-(9-{4-[(5Z,10Z,14Z,19Z)-10,15,20-Tris-(3,5-di-tert-butyl-phenyl)-porphyrin-5-yl]-phenyl}-[1,10]phenanthrolin-2-yl)-benzaldehyde 

Downstream Products

• 120086-02-4 C₁₄₈H₁₅₆N₁₀Zn₂ 
• 120086-01-3 C₁₂H₆N₂(C₆H₄)2(NC₄H₂)4H₂C(CC₆H₃(C(CH₃)3)2)3Zn(NC₄H₂)4C(CC₆H₃(C(CH₃)3)2)3 
• 120086-02-4 C₁₂H₆N₂(C₆H₄)2(Zn(NC₄H₂)4C(CC₆H₃(C(CH₃)3)2)3)2 

Relevant academic research and scientific papers

Various synthetic routes to a gable-like bis(porphyrin) constructed on a 1,10-phenanthroline chelate

Three different synthetic routes to obtain a gable-like bis(porphyrin) are described. The two porphyrins are covalently linked to a 2,9-diphenyl-l.,10- phenanthroline chelate. One way to gain access to the bis(porphyrin) relies on the simultaneous constru

Synthesis of bis-porphyrins containing a 2,9-diphenyl-1,10-phenanthroline spacer

The synthesis of bis-porphyrins disposed in an oblique fashion is described. The tetrapyrrole rings are linked via a 2,9-diphenyl-1,10-phenanthroline spacer. Two routes have been investigated: a step wise procedure and a direct strategy involving a double cyclisation step. From the bis-free base porphyrin, synthesized with an overall yield of 1% from 2,9-di(p-tolyl)-1,10-phenanthroline, an unsymmetrical zinc (II) porphyrin free base system was prepared and isolated in view of excited state energy and electron transfer.