120132-02-7

Basic information

• Product Name: (1R,2R,6R)-2-[1,3]Dioxolan-2-ylmethyl-3-formyl-6-hydroxy-cyclohex-3-enecarboxylic acid methyl ester
• Synonyms: (1R,2R,6R)-2-[1,3]Dioxolan-2-ylmethyl-3-formyl-6-hydroxy-cyclohex-3-enecarboxylic acid methyl ester
• CAS NO: 120132-02-7
• Molecular Weight: 270.282
• Mol File: 120132-02-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,2R,6R)-2-[1,3]Dioxolan-2-ylmethyl-3-formyl-6-hydroxy-cyclohex-3-enecarboxylic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2R,6R)-2-[1,3]Dioxolan-2-ylmethyl-3-formyl-6-hydroxy-cyclohex-3-enecarboxylic acid methyl ester(120132-02-7)
• EPA Substance Registry System: (1R,2R,6R)-2-[1,3]Dioxolan-2-ylmethyl-3-formyl-6-hydroxy-cyclohex-3-enecarboxylic acid methyl ester(120132-02-7)

Safety Data

• Hazardous Substances Data: 120132-02-7(Hazardous Substances Data)

Upstream product

• 79409-46-4 Methyl (2S,3R,4S)-4-(1,3-Dioxolan-2-ylmethyl)-3,4-dihydro-2-(2,3,4,6-tetraacetyl-β-D-glucopyranosyloxy)-3-vinyl-2H-pyran-5-carboxylate 
• 27856-66-2 O,O,O,O-tetraacetylsecologaninn 
• 19351-63-4 secologanin 
• 79409-45-3 Methyl (2S,3R,4S)-4-(1,3-Dioxolan-2-ylmethyl)-2-(β-D-glucopyranosyloxy)-3,4-dihydro-3-vinyl-2H-pyran-5-carboxylate 

Downstream Products

• 549-84-8 β-yohimbine 
• 2671-57-0 (+)-yohimbinone 
• 146-48-5 Yohimbine 
• 297131-94-3 (1R,2R,6R)-2-[1,3]Dioxolan-2-ylmethyl-6-hydroxy-3-{[2-(1H-indol-3-yl)-ethylamino]-methyl}-cyclohex-3-enecarboxylic acid methyl ester 

Relevant articles and documents

Enantiospecific synthesis of (-)-3-iso-19,20-dehydro-β-yohimbine from secologanin: A route to normal and pseudo stereoisomers of yohimbine

Hydrolysis of secologanin ethylene acetal at pH 7 resulted in stereoselective aldol cyclisation to a cyclohexene aldehyde, which, on reductive amination and cyclisation with tryptamine afforded (-)-3-iso-19,20- dehydro-β-yohimbine, converted into various normal and pseudo isomers of yohimbine. (C) 2000 Elsevier Science Ltd.