120159-46-8

Basic information

• Product Name: Cyclopentane, 1-bromo-3-methylene- (9CI)
• Synonyms: Cyclopentane, 1-bromo-3-methylene- (9CI)
• CAS NO: 120159-46-8
• Molecular Formula: C6H9Br
• Molecular Weight: 161.03966
• Product Categories: HALIDE
• Mol File: 120159-46-8.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopentane, 1-bromo-3-methylene- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentane, 1-bromo-3-methylene- (9CI)(120159-46-8)
• EPA Substance Registry System: Cyclopentane, 1-bromo-3-methylene- (9CI)(120159-46-8)

Safety Data

• Hazardous Substances Data: 120159-46-8(Hazardous Substances Data)

Upstream product

• 14548-32-4 4-methylenecyclopentene 
• 285-86-9 bicyclo[2.1.1]hexane 

Relevant articles and documents

Free Radical Reactions of Bicyclohexane and Bicycloheptane

t-Butoxyl radicals abstract hydrogen from C(2) of bicyclohexane (3) to give bicyclohexan-2-yl radicals (6).At T>250 K radicals (6) rearrange by β-scission to cyclopent-3-enylmethyl radicals; both species were observed by e.p.r. spectroscopy.In spite of the much greater ring strain the activation energy for rearrangement of (6) is about the same as that of cyclobutylmethyl radicals.Bromine atoms abstract hydrogen from C(2) of (3), but bis(trimethylsilyl)aminyl radicals abstract the bridgehead methine hydrogen at C(1) as well as the methylene hydrogensat C(2).There is very little abstraction of the bridgehead hydrogen in bicycloheptane by bis(trimethylsilyl)aminyl radicals.Thus, the greater bridgehead reactivity of (3) as compared with the bridge positions is not simply due to the lower selectivity of the bis(trimethylsilyl)aminyl radicals, but is an intrinsic property of the bicycloalkane.