1201685-85-9Relevant academic research and scientific papers
Bronsted acid catalyzed enantioselective semipinacol rearrangement for the synthesis of chiral spiroethers
Zhang, Qing-Wei,Fan, Chun-An,Zhang, Hai-Jun,Tu, Yong-Qiang,Zhao, Yu-Ming,Gu, Peiming,Chen, Zhi-Min
supporting information; experimental part, p. 8572 - 8574 (2009/12/29)
A new twist: The catalytic asymmetric semipinacol rearrangement reaction of 2oxo allylic alcohols 1 in the presence of a catalytic amount of chiral phosphoric acid (R)-2a or its silver salt (R)-2b affords enantiomerically pure spiroethers 3.
