120174-12-1

Basic information

• Product Name: 2-(2-aminophenyl)dodecahydro-9a,9b-dimethyl-2-(methylthio)-1H-benzinden-1-one
• CAS NO: 120174-12-1
• Molecular Weight: 357.56
• Mol File: 120174-12-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2-aminophenyl)dodecahydro-9a,9b-dimethyl-2-(methylthio)-1H-benzinden-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-aminophenyl)dodecahydro-9a,9b-dimethyl-2-(methylthio)-1H-benzinden-1-one(120174-12-1)
• EPA Substance Registry System: 2-(2-aminophenyl)dodecahydro-9a,9b-dimethyl-2-(methylthio)-1H-benzinden-1-one(120174-12-1)

Safety Data

• Hazardous Substances Data: 120174-12-1(Hazardous Substances Data)

Upstream product

• 120174-04-1 (3aα,5aβ,9aα,9bα)-dodecahydro-9a,9b-dimethyl-1-oxo-9bH-benzindene 
• 120174-09-6 (3aα,5aβ,9aα,9bβ)-dodecahydro-9a,9b-dimethyl-1-oxo-9bH-benzindene 
• 120174-00-7 (4aR,8aS)-8a-Methyl-1-[3-(tetrahydro-pyran-2-yloxy)-prop-1-ynyl]-decahydro-naphthalen-1-ol 
• 120174-08-5 (3aα,5aβ,9aα,9bα)-dodecahydro-9a-methyl-1-oxo-9bH-benzindene-9b-acetaldehyde 
• 120174-06-3 (3aα,5aβ,9aα,9bα)-dodecahydro-9a-methyl-9b-(2-propenyl)-1-oxo-9bH-benzindene 
• 120174-07-4 (3aα,5aβ,9aα)-3,3a,4,5,5a,6,7,8,9,9a-decahydro-9a-methyl-1-(2-propenyloxy)-2H-benzindene 
• 120174-02-9 (5a-trans)-2,3,4,5,5a,6,7,8,9,9a-decahydro-9a-methyl-1H-benzinden-1-one 
• 120292-87-7 1,1-ethylenedioxy-9β-methyl-trans-decalin 
• 73284-92-1 (+)-(4aS,8aS)-1,1-(1,2-Ethylenedioxy)-1,2,3,4,4aα,5,6,7,8,8a-decahydro-8aβ-methyl-6-oxonaphthalene 
• 6102-38-1 (4aR,8aS)-8a-methyloctahydronaphthalen-1(2H)-one 
• 61950-54-7 (8aS)-1,1-(1,2-ethylenedioxy)-1,2,3,4,6,7,8,8a-octahydro-8a-methyl-6-oxonaphthalene 
• 120174-10-9 (3aS,5aR,9aS,9bR)-9a,9b-Dimethyl-2-methylsulfanyl-dodecahydro-cyclopenta[a]naphthalen-1-one 
• 62-53-3 aniline 
• 120174-10-9 (3aα,5aβ,9aα,9bβ)-dodecahydro-9a,9b-dimethyl-2-(methylthio)-1H-benzinden-1-one 

Downstream Products

• 120174-16-5 (3aα,5aβ,9aα,9bα)-dodecahydro-9a,9b-dimethyl-2-(phenylamino)-1H-benzinden-1-one 
• 120228-97-9 (3aα,5aβ,9aα,9bβ)-dodecahydro-9a,9b-dimethyl-2-(phenylamino)-1H-benzinden-1-one 

Relevant articles and documents

Indole Diterpene Synthetic Studies. 2. First-Generation Total Synthesis of (-)-Paspaline

We record here a full account of the first total synthesis of (-)-paspaline (1), the simplest member of a rapidly growing class of architecturally complex diterpene indole alkaloids, many of which possess potent tremorgenic activity.In terms of sequential annulation, the strategy involves the following operations: DE -> CDE -> CDEF -> ABCDEF.Proceeding in 23 steps from Wieland-Miescher ketone, the synthesis afforded (-)-paspaline (1) in high enantiomeric purity.