1201908-86-2

Basic information

• Product Name: 6,6'-(2,5-bis(2-(tert-butyldimethylsilyloxy)ethyl)-1,4-phenylene)bis(3-bromopyridine)
• Synonyms: 6,6'-(2,5-bis(2-(tert-butyldimethylsilyloxy)ethyl)-1,4-phenylene)bis(3-bromopyridine)
• CAS NO: 1201908-86-2
• Molecular Weight: 706.708
• Mol File: 1201908-86-2.mol

Chemical Properties

• CAS DataBase Reference: 6,6'-(2,5-bis(2-(tert-butyldimethylsilyloxy)ethyl)-1,4-phenylene)bis(3-bromopyridine)(CAS DataBase Reference)
• NIST Chemistry Reference: 6,6'-(2,5-bis(2-(tert-butyldimethylsilyloxy)ethyl)-1,4-phenylene)bis(3-bromopyridine)(1201908-86-2)
• EPA Substance Registry System: 6,6'-(2,5-bis(2-(tert-butyldimethylsilyloxy)ethyl)-1,4-phenylene)bis(3-bromopyridine)(1201908-86-2)

Safety Data

• Hazardous Substances Data: 1201908-86-2(Hazardous Substances Data)

Upstream product

• 624-28-2 2,5-dibromopyridine 
• 1201908-85-1 (2,2'-(2,5-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1,4-phenylene)bis(ethane-2,1-diyl))bis(oxy)bis(tert-butyldimethylsilane) 

Relevant articles and documents

Poly(3-hexylthiophene)-block-poly(pyridinium phenylene)s: Block polymers of p-and n-type semiconductors

Conjugated crystalline-crystalline donor-acceptor-donor block copolymer semiconductors, with regioregular poly(3-hexylthiophene) as a donor (p-type) block and poly(pyridinium pheneylene) as an acceptor (n-type) block within the backbone, were produced by sequential Grignard metathesis synthesis of poly(3-hexylthiophene), a Yamamoto-type cross-coupling polymerization- cyclization sequence. These conjugated block copolymers are soluble in organic solvents and display broad optical absorption bands extending close to the near-infrared region. They show reversible ambipolar redox properties with high electron affinities of 3.8-4.0 eV as well as useful ionization potentials of 5.1 eV that are characteristic of the respective blocks. Block copolymers from p- and n-type organic semiconductors are of interest for the formation of nanostructured bulk heterojunctions in photovoltaic devices.

Poly(pyridinium phenylene)s: Water-soluble N-type polymers

(Chemical Equation Presented) Poly(pyridinium phenylene) conjugated polymers are synthesized by a cross-coupling and cyclization sequence. These polyelectrolytes are freely soluble in water and display high degrees of electroactivity. When reduced (n-doped) these materials display in situ conductivities as high as 160 S/cm. The high conductivity is attributed to the planar structure that is enforced by the cyclic structures of the polymer. The electron affinities are compared to PCBM, a C60 based n-type material. We find that these polymers undergo excited state electron transfer reactions with other donor conjugated polymers and hence may find utility in photovoltaic devices.