1202033-05-3

Basic information

• Product Name: (R)-3-tert-butyl-4-phenyl-2,3-dihydrobenzo[d][1,3]oxaphosphole oxide
• Synonyms: (R)-3-tert-butyl-4-phenyl-2,3-dihydrobenzo[d][1,3]oxaphosphole oxide
• CAS NO: 1202033-05-3
• Molecular Weight: 286.31
• Mol File: 1202033-05-3.mol

Chemical Properties

• CAS DataBase Reference: (R)-3-tert-butyl-4-phenyl-2,3-dihydrobenzo[d][1,3]oxaphosphole oxide(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-3-tert-butyl-4-phenyl-2,3-dihydrobenzo[d][1,3]oxaphosphole oxide(1202033-05-3)
• EPA Substance Registry System: (R)-3-tert-butyl-4-phenyl-2,3-dihydrobenzo[d][1,3]oxaphosphole oxide(1202033-05-3)

Safety Data

• Hazardous Substances Data: 1202033-05-3(Hazardous Substances Data)

Upstream product

• 1202032-91-4 tert-butyl(2,6-dimethoxyphenyl)(methyl)phosphine oxide 
• 1202033-25-7 (R)-3-(tert-butyl)-4-hydroxy-2H-benzo[ d][1,3]oxaphosphole 3-oxide 
• 1202032-97-0 (R)-3-(tert-butyl)-3-oxido-2H-benzo[d][1,3]oxaphosphol-4-yl ((1S,2R,5S)-2-isopropyl-5-methylcyclohexyl) carbonate 
• 1202032-95-8 racemic 3-tert-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphol-4-ol oxide 
• 1202032-93-6 tert-butyl(2,6-dimethoxyphenyl)(iodomethyl)phosphine oxide 
• 151-10-0 1,3-Dimethoxybenzene 
• 1202032-99-2 (R)-3-(tert-butyl)-3-oxido-2H-benzo[d][1,3]oxaphosphol-4-yl trifluoromethanesulfonate 
• 98-80-6 phenylboronic acid 

Downstream Products

• 1202033-13-3 (2S,2'S,3R,3'R)-3,3'-di-tert-butyl-4,4'-diphenyl-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole bisoxide 
• 1246888-87-8 (S)-3-tert-butyl-4-phenyl-2,3-dihydrobenzo[d][1,3]oxaphosphole 
• 2301856-53-9 C₃₄H₃₆O₂P₂ 

Relevant articles and documents

NOVEL CHIRAL PHOSPHORUS LIGANDS

The invention relates to a series of novel chiral phosphorus ligands of formulae (Ia) and (Ib): wherein R, 1 - rR> 4 and X are as defined herein. The invention also relates to chiral metal complexes prepared with these chiral phosphorus ligands. The chira

Novel, tunable, and efficient chiral bisdihydrobenzooxaphosphole ligands for asymmetric hydrogenation

"Chemical Equation Presented" A series of novel, efficient, air-stable, and tunable chiral bisdihydrobenzooxaphosphole ligands (BIBOPs) were developed for rhodium-catalyzed hydrogenations of various functionalized olefins such as α-ary lenam ides, α-(acylamino)acrylic acid derivatives, β-(acylamino)acrylates, and dimethyl itaconate with excellent enantioselectivities (up to 99% ee) and reactivities (up to 2000 TON)