1202033-54-2Relevant academic research and scientific papers
Novel, tunable, and efficient chiral bisdihydrobenzooxaphosphole ligands for asymmetric hydrogenation
Tang, Wenjun,Qu, Bo,Capacci, Andrew G.,Rodriguez, Sonia,Wei, Xudong,Haddad, Nizar,Narayanan, Bikashandarkoil,Ma, Shengli,Grinberg, Nelu,Yee, Nathan K.,Krishnamurthy, Dhileep,Senanayake, Chris H.
, p. 176 - 179 (2010)
"Chemical Equation Presented" A series of novel, efficient, air-stable, and tunable chiral bisdihydrobenzooxaphosphole ligands (BIBOPs) were developed for rhodium-catalyzed hydrogenations of various functionalized olefins such as α-ary lenam ides, α-(acylamino)acrylic acid derivatives, β-(acylamino)acrylates, and dimethyl itaconate with excellent enantioselectivities (up to 99% ee) and reactivities (up to 2000 TON)
