1202208-33-0Relevant academic research and scientific papers
Synthesis and structure of novel 1,2,4-triazole derivatives containing the 2,4-dinitrophenylthio group
Ding, Qichun,Lei, Xinxiang,Jin, Jianyu,Zhang, Lixue,Du, Huiai,Zhang, Haile
experimental part, p. 114 - 119 (2009/10/02)
Some novel 1,2,4-triazole derivatives containing the 2,4-dinitrophenylthio group have been synthesised in high yields by means of the reactions of 3-substituted-4-amino -1H-1,2,4-triazole-5(4H)-thiones or (S-3-aryl-4- (benzylideneamino)-1H-l,2,4-triazole-5(4H)-thiones with 1-chloro-2,4- dinitrobenzene. The (S-3-aryl-4-(benzylideneamino)-1H-1,2,4-triazole-5(4H)- thiones were prepared by the reaction of 4-amino-3-aryl-2H-1,2,4-triazole-3(4H)- thiones and diverse aromatic aldehydes. The 2, 4-dinitrophenyl group linked to the S atom, not to the N atom, was confirmed by the crystal structures. The structures of all the compounds were determined by elemental analysis, IR, MS, 1H NMR and 13C NMR.
