120236-20-6

Basic information

• Product Name: (2S,3R)-ethyl 2-(benzamidomethyl)-3-hydroxybutanoate
• Synonyms: (2S,3R)-ethyl 2-(benzamidomethyl)-3-hydroxybutanoate
• CAS NO: 120236-20-6
• Molecular Weight: 265.309
• Mol File: 120236-20-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2S,3R)-ethyl 2-(benzamidomethyl)-3-hydroxybutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-ethyl 2-(benzamidomethyl)-3-hydroxybutanoate(120236-20-6)
• EPA Substance Registry System: (2S,3R)-ethyl 2-(benzamidomethyl)-3-hydroxybutanoate(120236-20-6)

Safety Data

• Hazardous Substances Data: 120236-20-6(Hazardous Substances Data)

Upstream product

• 69396-18-5 ethyl 2-(benzamidomethyl)-3-oxobutanoate 

Relevant articles and documents

DIOPHEP, a chiral diastereoisomeric bisphosphine ligand: synthesis and applications in asymmetric hydrogenations

Novel optically active diphosphine ligands, known as DIOPHEP, have been designed and synthesized starting from a derivative of tartaric acid. The ligands conjugate the sp3 chirality of the precursor of DIOP with the atropisomeric chirality of a biaryl scaffold. The stereorecognition abilities of DIOPHEP-Ru complex catalysts have been investigated in the asymmetric catalytic hydrogenation of some standard substrates suggesting a close relationship between dihedral angles and enantioselectivity.

Dynamic kinetic resolution of β′-keto-β-amino esters using Ru-DTBM-Sunphos catalyzed asymmetric hydrogenation

A convenient method for the enantioselective synthesis of β′-hydroxy-β-amino esters was developed through intensive investigations of the reaction conditions. Dichloromethane (DCM)/2,2,2- trifluoroethanol (TFE) and 1,2-dichloroethane (DCE)/TFE combination