1202381-72-3

Basic information

• Product Name: (1S,3R,E)-1-cyclohexyl-2-((trimethylsilyl)methylene)pentane-1,3-diol
• Synonyms: (1S,3R,E)-1-cyclohexyl-2-((trimethylsilyl)methylene)pentane-1,3-diol
• CAS NO: 1202381-72-3
• Molecular Weight: 270.488
• Mol File: 1202381-72-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,3R,E)-1-cyclohexyl-2-((trimethylsilyl)methylene)pentane-1,3-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,3R,E)-1-cyclohexyl-2-((trimethylsilyl)methylene)pentane-1,3-diol(1202381-72-3)
• EPA Substance Registry System: (1S,3R,E)-1-cyclohexyl-2-((trimethylsilyl)methylene)pentane-1,3-diol(1202381-72-3)

Safety Data

• Hazardous Substances Data: 1202381-72-3(Hazardous Substances Data)

Upstream product

• 18269-90-4 (R)-1-(trimethylsilyl)pent-1-yn-3-ol 
• 2043-61-0 cyclohexanecarbaldehyde 

Relevant articles and documents

Diastereoselective synthesis of syn-1,3-diols by titanium-mediated reductive coupling of propargylic alcohols

(Figure presented) A titanium-mediated, hydroxy-directed reductive coupling reaction of propargylic alcohols and aldehydes/ketones Is described. Excellent diastereoselectivity and synthetically useful yields have been obtained for a range of substrates. This transformation has enabled a highly convergent three-component approach to syn-1,3-diols using (trimethylsilyl)acetylene as a C1 linchpin.