1202582-52-2Relevant academic research and scientific papers
In situ dearomatisation/alkylation of arylphosphane derivatives
Stankevic, Marek,Wojcik, Karolina,Jaklinska, Magdalena,Pietrusiewicz, K. Michal
experimental part, p. 2521 - 2534 (2012/06/01)
The dearomatisation of aryldialkylphosphane-boranes and aryldialkylphosphane oxides under Birch reduction conditions, followed by treatment with reactive alkyl halides, provides the corresponding α-functionalised (cyclohexa-1,4-dien-3-yl)phosphane derivatives. This reaction offers a method of choice for the synthesis of bulky (cyclohexadienyl)phosphanes.
Birch reduction of aryldialkylphosphine-boranes
Stankevi?, Marek,Micha? Pietrusiewicz
supporting information; experimental part, p. 7093 - 7095 (2010/03/03)
Aryldialkylphosphine-boranes undergo facile Birch-type reduction to afford cyclohexadienyldialkylphosphine-boranes in high yields. Judicious choice of the metal and the reaction conditions allows for complete elimination of the undesired P-Ph bond cleavag
