1202696-10-3

Basic information

• Product Name: C₁₈H₃₀N₂O₄SSi
• Synonyms: C₁₈H₃₀N₂O₄SSi
• CAS NO: 1202696-10-3
• Molecular Weight: 398.599
• Mol File: 1202696-10-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₈H₃₀N₂O₄SSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₈H₃₀N₂O₄SSi(1202696-10-3)
• EPA Substance Registry System: C₁₈H₃₀N₂O₄SSi(1202696-10-3)

Safety Data

• Hazardous Substances Data: 1202696-10-3(Hazardous Substances Data)

Upstream product

• 1202696-06-7 N-Boc-cis-4-tert-butyldimethylsiloxy-L-proline amide 

Relevant articles and documents

Highly diastereo- and enantioselective direct aldol reactions by 4-tert-butyldimethylsiloxy-substituted organocatalysts derived from N-prolylsulfonamides in water

A new set of 4-tert-butyldimethylsiloxy-substituted organocatalysts derived from N-prolylsulfonamide has been designed and proved to be effective in catalyzing the direct aldol reactions of cyclic ketones with a series of aromatic aldehydes. Furthermore, to the best of our knowledge, there are no reports on the aldol reaction generating the products in very good yields (>99%) and with excellent diastereoselectivities up to >99:1 and enantioselectivities up to >99% by using lower catalyst loadings (only 3 mol %), without using any additives in a large amount of water under mild conditions.