1202752-63-3

Basic information

• Product Name: 3-chloro-5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)cyclohex-2-en-1-one
• Synonyms: 3-chloro-5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)cyclohex-2-en-1-one
• CAS NO: 1202752-63-3
• Molecular Weight: 304.644
• Mol File: 1202752-63-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3-chloro-5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)cyclohex-2-en-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-chloro-5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)cyclohex-2-en-1-one(1202752-63-3)
• EPA Substance Registry System: 3-chloro-5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)cyclohex-2-en-1-one(1202752-63-3)

Safety Data

• Hazardous Substances Data: 1202752-63-3(Hazardous Substances Data)

Upstream product

• 950908-44-8 2-pentafluoropropionyl-5,5-dimethylcyclohexane-1,3-dione 

Downstream Products

• 1202752-81-5 5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)-3-(pyrrolidin-1-yl)cyclohex-2-en-1-one 
• 1202752-84-8 5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)-3-(1-piperidino)cyclohex-2-en-1-one 
• 1202752-69-9 5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)-3-phenylaminocyclohex-2-en-1-one 
• 1202752-78-0 3-(4-fluorobenzylamino)-5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)cyclohex-2-en-1-one 
• 1202752-75-7 3-benzylamino-5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)cyclohex-2-en-1-one 
• 1202752-72-4 3-(4-fluorophenylamino)-5,5-dimethyl-2-(2,2,3,3,3-pentafluoropropanoyl)cyclohex-2-en-1-one 
• 1313409-43-6 3-(4-fluorophenylamino)-5,5-dimethyl-2-(2,2,3,3,3-pentafluoro-1-hydroxypropyl)cyclohex-2-en-1-one 
• 1313409-51-6 3-benzylamino-5,5-dimethyl-2-(2,2,3,3,3-pentafluoro-1-hydroxypropyl)cyclohex-2-en-1-one 
• 1313409-37-8 5,5-dimethyl-2-(2,2,3,3,3-pentafluoro-1-hydroxypropyl)-3-phenylaminocyclohex-2-en-1-one 

Relevant articles and documents

Regioselective Synthesis of Polyfluoroalkyl Substituted 6,7-Dihydrobenzisoxazolones

Regioselective methods for synthesis of hitherto unreported both 6,7-dihydro-1,2-benzisoxazol-4(5H)-ones and 6,7-dihydro-2,1-benzisoxazol-4(5H)-ones with perfluoroalkyl or halogenodifluoromethyl substituents have been developed. 3-Polyfluoroalkyl-6,7-dihydro-1,2-benzisoxazol-4(5H)-ones were prepared by the cyclocondensation of 2-polyfluoroalkanoylcyclohexane-1,3-diones with hydroxylamine. The regioisomeric 3-polyfluoroalkyl-6,7-dihydro-2,1-benzisoxazol-4(5H)-ones were synthesized by the transformation of 2-polyfluoroalkanoylcyclohexane-1,3-diones into their vinylogous chlorides, followed by the interaction of obtained crude 3-chloro-2-polyfluoroalkanoyl-2-cyclohexen-1-ones with sodium azide in dimethylformamide.

Regioselective reduction of 2-perfluoroalkanoylcyclohexane-1,3-diones and their enamino derivatives

Ionic hydrogenation of 2-perfluoroalkanoylcyclohexane-1,3-diones and their endocyclic enamino derivatives containing a secondary amino group by the action of triethylsilane in trifluoroacetic acid in the presence of a catalytic amount of lithium perchlora