1202783-53-6Relevant articles and documents
Cobalt-mediated B-H activation and cyclopentadienyl-participated diels-alder addition in the reaction of a 16e CpCo complex containing an o-carborane-1,2-dithiolato ligand with HC≡C-C(O)Ph
Li, Yuguang,Jiang, Qibai,Li, Yizhi,Yan, Hong,Bregadze, Vladimir I.
, p. 4 - 6 (2010)
The reaction of the 16e half-sandwich complex CpCo(S2C 2B10H10) (1) with HC≡C-C(O)Ph leads to a 17e complex 2 containing a blcyclo[2.2.1]heptene unit at the B3/B6 site of carborane. In the presence of air, water and silica 2 converts to two 16e complexes, 3 and 4, bearing new types of functionalized groups.