1202785-03-2Relevant academic research and scientific papers
A stereodivergent synthesis of all stereoisomers of centrolobine: Control of selectivity by a protecting-group manipulation
Schmidt, Bernd,Hoelter, Frank
experimental part, p. 11948 - 11953 (2010/05/18)
All stereoisomers of the natural product centrolobine are selectively synthesized, by starting from a common precursor. Key steps are an enantioselective allylation with enantiomerically pure allylsilanes, a tandem ring-closing metathesis-isomerization re
