1202785-08-7Relevant academic research and scientific papers
Enantioselective total synthesis of (-)-ericanone
Dias, Luiz C.,Kuroishi, Paula K.,Polo, Ellen C.,De Lucca Jr., Emílio C.
, p. 980 - 982 (2013/02/25)
The first total synthesis of (-)-ericanone was achieved in 10 steps with a 16% overall yield from p-hydroxybenzaldehyde. Notable features of this stereocontrolled approach include a Keck allylation to install the stereocenter at C3 and a 1,5-anti aldol reaction to install the hydroxyl group at C7.
A stereodivergent synthesis of all stereoisomers of centrolobine: Control of selectivity by a protecting-group manipulation
Schmidt, Bernd,Hoelter, Frank
supporting information; experimental part, p. 11948 - 11953 (2010/05/18)
All stereoisomers of the natural product centrolobine are selectively synthesized, by starting from a common precursor. Key steps are an enantioselective allylation with enantiomerically pure allylsilanes, a tandem ring-closing metathesis-isomerization re
