120293-93-8Relevant articles and documents
Ichinose,I. et al.
, p. 605 - 607 (1978)
An efficient asymmetric synthesis of the higher dipteran juvenile hormone III bisepoxide
Rickards, Rodney W.,Thomas, Richard D.
, p. 8369 - 8372 (2007/10/02)
(2E,6S,7S,10R) - Juvenile hormone III bisepoxide, the putative characteristic juvenile hormone of higher dipteran insects, has been synthesised efficiently and in high stereochemical purity from geraniol by application of Sharpless asymmetric epoxidation and dihydroxylation procedures.
Synthesis of four stereoisomers of the higher dipteran juvenile hormone III bisepoxide
Rickards, Rodney W.,Thomas, Richard D.
, p. 8137 - 8140 (2007/10/02)
The 6S,7S,10R-, 6S,7S,10S-, 6R,7R,10S-, and 6R,7R,10R-stereoisomers of the juvenile hormone III bisepoxide from higher Dipteran insects have been synthesised in high stereoisomeric purity. The route involves Sharpless epoxidation of geraniol to enantiomeric epoxyalcohols, which are each elaborated via separable diastereomeric bromohydrins.