120294-04-4Relevant articles and documents
New synthetic strategies toward pure two-component triglycerides
Gras, Jean-Louis,Bonfanti, Jean-Fran?ois
, p. 1835 - 1837 (1999)
Pure two-component triglycerides were prepared following new synthetic strategies that involve the acylolytic cleavage of glycerol acetals.
Lipase-mediated desymmetrization of glycerol with aromatic and aliphatic anhydrides
Batovska, Daniela I.,Tsubota, Shuichirou,Kato, Yasuo,Asano, Yasuhisa,Ubukata, Makoto
, p. 3551 - 3559 (2007/10/03)
Chirazyme L-2 (Candida antarctica) catalyzed esterification of glycerol with aromatic and aliphatic anhydrides in 1,4-dioxane is described. All the aromatic monoacylglycerols (MAGs) were produced as (R)-enantiomers, while aliphatic MAGs were obtained either as racemic mixtures or the (S)-enantiomers. The influence of substituted aromatic rings, chain length, and presence of a conjugated double bond in the acyl donor moiety on the enantiotopic selectivity as well as the efficiency of the enzyme was studied.