120342-90-7Relevant academic research and scientific papers
Application of molecular dynamics technique to identification of products obtained by reaction of ethoxycarbonylcarbene with various substrates with the use of GC-MS method
Zenkevich,Kharicheva,Kostikov
, p. 1567 - 1573 (2007/10/03)
In reaction of ethoxycarbonylcarbene with various substrates may occur either cyclopropanes formation or its insertion into C-O and C-H bonds. To support the GC-MS identification of the reaction products a method is suggested for interpretation of the gas-chromatographic retention indices (RI) thereof with the use of an expression ΔI - aΔE+b (a0) where ΔI are the experimentally determined differences between RI of the products and reagents, and aΔE are the corresponding differences of the intramolecular vibration and rotation energies estimated by molecular dynamics procedure.
FACILE CATALYTIC METHODS FOR INTERMOLECULAR GENERATION OF ALLYLIC OXONIUM YLIDES AND THEIR STEREOSELECTIVE -SIGMATROPIC REARRANGEMENT
Doyle, Michael P.,Bagheri, Vahid,Harn, Nancy K.
, p. 5119 - 5122 (2007/10/02)
Allylic oxonium ylides, generated by rhodium(II) acetate-catalyzed decomposition of diazo carbonyl compounds in the presence of allyl methyl ethers, undergo the -sigmatropic rearrangement with a high degree of diasteroselectivity.
