120342-97-4Relevant articles and documents
FACILE CATALYTIC METHODS FOR INTERMOLECULAR GENERATION OF ALLYLIC OXONIUM YLIDES AND THEIR STEREOSELECTIVE -SIGMATROPIC REARRANGEMENT
Doyle, Michael P.,Bagheri, Vahid,Harn, Nancy K.
, p. 5119 - 5122 (2007/10/02)
Allylic oxonium ylides, generated by rhodium(II) acetate-catalyzed decomposition of diazo carbonyl compounds in the presence of allyl methyl ethers, undergo the -sigmatropic rearrangement with a high degree of diasteroselectivity.