1203493-75-7Relevant academic research and scientific papers
InI3/me3sii-catalyzed direct alkylation of enol acetates using alkyl acetates or alkyl ethers
Onishi, Yoshiharu,Nishimoto, Yoshihiro,Yasuda, Makoto,Baba, Akio
supporting information; experimental part, p. 1223 - 1225 (2011/11/29)
A combined Lewis acid of InI3 and Me3SiI was used to catalyze the direct coupling reactions of enol acetates with alkyl acetates or alkyl ethers without generating metal waste. The easily-handled alkylating reagents enlarged the application area of this coupling reaction. 2011 The Chemical Society of Japan.
InCl3/Me3SiBr-catalyzed direct coupling between silyl ethers and enol acetates
Onishi, Yoshiharu,Nishimoto, Yoshihiro,Yasuda, Makoto,Baba, Akio
supporting information; experimental part, p. 2762 - 2765 (2011/08/02)
A combined Lewis acid catalyst of InCl3 and Me3SiBr promoted the direct use of enol acetates in the coupling with low-reactive silyl ethers, in which functional groups including ketones and aldehydes survived. Sterically hindered silyl ethers such as ROSiEt3, ROSiPh3, ROSit-BuMe2, and ROSii-Pr3 were also applicable.
α-Alkylation of carbonyl compounds by direct addition of alcohols to Enol acetates
Nishimoto, Yoshihiro,Onishi, Yoshiharu,Yasuda, Makoto,Baba, Akio
supporting information; experimental part, p. 9131 - 9134 (2010/03/01)
A practical α-alkylation of ketones and aldehydes has been achieved by the direct addition of alcohols to enol acetates. The moderate Lewis acidity of InI3, CaBr3, and FeBr3 is a key factor in the catalytic cycle, and many different alcohols and enol acetates have been successfully used in this procedure.
