1203605-75-7Relevant academic research and scientific papers
Dioxygen activation under ambient conditions: Cu-catalyzed oxidative amidation-diketonization of terminal alkynes leading to α-ketoamides
Chun, Zhang,Ning, Jiao
supporting information; experimental part, p. 28 - 29 (2010/03/25)
(Figure Presented) A novel Cu-catalyzed oxidative amidation-diketonization reaction of terminal alkynes leading to α-ketoamides has been developed. This chemistry offers a valuable mechanistic insight into this novel Cu catalysis via a radical process. O2 not only participates as the ideal oxidant but also undergoes dioxygen activation under ambient conditions in this transformation.
