120380-37-2

Upstream product

• 142308-58-5 {(η-6-C6H5CH3)RuH(PCy3)2}BF4 
• 76-05-1 trifluoroacetic acid 
• 112320-11-3 RuH₂(H₂)2(tricyclohexylphosphine)2 

Downstream Products

• 120389-49-3 Ru(η2-H2)(OCOCF3)2{P(C6H11)3}2 
• 120389-50-6 RuH₂(OCOCF₃)2(P(C₆H₁₁)3)2 

Relevant academic research and scientific papers

A New Class of Dihydrogen Complexes containing Oxygen Donor Ligands. Preparation of RuH(η2-H2)(OCOCF3)2 and of the Equilibrated Mixture RuH2(OCOCF3)22/Ru(η2-H2)(OCOCF3)22

The protonation of RuH2(H2)2(PCy3)2 (1) (Cy = cyclohexyl) with CF3CO2H in acetone leads to the hydrido dihydrogen derivative RuH(H2)(OCOCF3)(PCy3)2 (2), which reacts further in hexane to yield a very reactive RuIV dihydride, RuH2(OCOCF3)2(PCy3)