120400-88-6Relevant articles and documents
Enantioselective fluorination of α-branched aldehydes and subsequent conversion to α-hydroxyacetals via stereospecific C-F bond cleavage
Shibatomi, Kazutaka,Kitahara, Kazumasa,Okimi, Takuya,Abe, Yoshiyuki,Iwasa, Seiji
, p. 1388 - 1392 (2016/02/05)
The highly enantioselective fluorination of α-branched aldehydes was achieved using newly developed chiral primary amine catalyst 1. Furthermore, the C-F bond cleavage of the resulting α-fluoroaldehydes proceeded smoothly under alcoholic alkaline conditio
AMINE COMPOUND, OPTICALLY ACTIVE AMINE, ASYMMETRIC CATALYST INCLUDING OPTICALLY ACTIVE AMINE, AND MANUFACTURING METHOD OF OPTICALLY ACTIVE HALOGEN COMPOUND USING ASYMMETRIC CATALYST
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Paragraph 0088, (2018/11/22)
PROBLEM TO BE SOLVED: To provide a novel optically active amine; a novel asymmetric catalyst including the optically active amine; and a manufacturing method of an optically active halogen compound using the asymmetric catalyst via high-efficiency asymmet
New synthetic routes to 2-fluoro-2-phenylalkanoic acids
Goj, Olav,Haufe, Guenter
, p. 1289 - 1294 (2007/10/03)
2-Fluoro-2-phenylalkanoic acids 2 are obtained by oxidation of the corresponding β-fluoro-β-phenyl alcohols 6. These compounds are shown to be accessible by two alternative pathways, either by bromo fluorination of α-alkyl styrenes 3, subsequent bromine-b
