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(1R,2S,3S,4S)-2-Methyl-3-((R)-toluene-4-sulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • (1R,2S,3S,4S)-2-Methyl-3-((R)-toluene-4-sulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester

    Cas No: 120410-03-9

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  • 120410-03-9 Structure
  • Basic information

    1. Product Name: (1R,2S,3S,4S)-2-Methyl-3-((R)-toluene-4-sulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester
    2. Synonyms: (1R,2S,3S,4S)-2-Methyl-3-((R)-toluene-4-sulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester
    3. CAS NO:120410-03-9
    4. Molecular Formula:
    5. Molecular Weight: 320.453
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 120410-03-9.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1R,2S,3S,4S)-2-Methyl-3-((R)-toluene-4-sulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1R,2S,3S,4S)-2-Methyl-3-((R)-toluene-4-sulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester(120410-03-9)
    11. EPA Substance Registry System: (1R,2S,3S,4S)-2-Methyl-3-((R)-toluene-4-sulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid ethyl ester(120410-03-9)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 120410-03-9(Hazardous Substances Data)

120410-03-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 120410-03-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,0,4,1 and 0 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 120410-03:
(8*1)+(7*2)+(6*0)+(5*4)+(4*1)+(3*0)+(2*0)+(1*3)=49
49 % 10 = 9
So 120410-03-9 is a valid CAS Registry Number.

120410-03-9Relevant articles and documents

The Asymmetric Diels-Alder Cycloaddition Using Ethyl(-)-(Z)-(R)s-2-methyl-3-(p-tlylsulfinyl)propenoate: Application to an Enantioselective Synthesis of (+)-epi-β-Santalene

Arai, Yoshitsugu,Yamamoto, Masatoshi,Koizumi, Toru

, p. 467 - 474 (2007/10/02)

The Diels-Alder reaction of ethyl (-)-(Z)-(R)s-2-methyl-3-(p-tolylsulfinyl)propenoate (6) with cyclopentadiene gave the adducts, 7, 8, and 9 in a high diastereoselective manner.The cycloadduct 7 was transformed into the acetal (-)-25.The racemic 25 was used as an intermediate in the synthesis of (+/-)-β-santalol.Thus, the chiral acetal (-)-25 should provide a route to (-)-Β-santalol.The cycloadduct 8 was converted into (+)-epi-β-santalene in 11 steps.

HIGHLY DIASTEREOSELECTIVE DIELS-ALDER REACTION OF OPTICALLY ACTIVE ETHYL 2-p-TOLYLSULFINYLMETHYLENEPROPIONATE WITH CYCLOPENTADIENE

Koizumi, Toru,Hakamada, Ichiro,Yoshii, Eiichi

, p. 87 - 90 (2007/10/02)

Stereochemistry of the Diels-Alder reaction of ethyl Z- and E-2-p-tolylsulfinylmethylenepropionate with cyclopentadiene has been studied.The high diastereoselectivity was observed especially in the case of exo-cycloaddition.

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