120410-57-3Relevant academic research and scientific papers
Solid-state chemistry of molecular metal oxide clusters. Reactions of microporous [(Ph3P)2IrH2]3PW12O 40 with small organic molecules
Siedle,Newmark
, p. 1442 - 1450 (2008/10/08)
The heterogeneous reactions of [(Ph3P)2IrH2]3PW12O 40 with CO, PF3, C2H4, C2H2, CH3CH=CH2, c-C5H8, C6H6, CH3C6H5, 2,3-dimethyl-1,3-butadiene, isoprene, butadiene, Me3SiH, C2F4, CF3CF=CF2, CF2=CFCl, CH3C(O)H, ethylene oxide, CH3OH, and H2O are described. The chemistry can be described in terms of either addition of iridium to a substrate C-H bond to form intermediates that may optionally eliminate H2 or addition of Ir-H to a C=C bond. It is proposed that these reactants gain access to essentially all of the iridium sites by dissolving in the hydrophobic regions of the lattice of the low surface area iridium oxometalate.
