120414-30-4Relevant articles and documents
DIELS-ALDER REACTIONS OF 2-AZADIENES. DIASTEREOSELECTIVE SYNTHESES OF 2-AZABICYCLOOCTAN-2-ONES AND OF 2,3,4-SUBSTITUTED CYCLOHEXANONES
Rivera, M.,Lamy-Schelkens, H.,Sainte, F.,Mbiya, K.,Ghosez, L.
, p. 4573 - 4576 (2007/10/02)
Glutarimide is readily disilylated to yield the cyclic 2-azadiene 1 which reacts with open-chain dienophiles with surprisingly high exo-selectivity.The resulting 2-aza-bicyclooctan-3-ones are stereoselectively transformed into substituted cyclohexa