1204348-75-3Relevant academic research and scientific papers
Electromeric rhodium radical complexes
Puschmann, Florian Frank,Harmer, Jeffrey,Stein, Daniel,Rueegger, Heinz,De Bruin, Bas,Gruetzmacher, Hansjoerg
, p. 385 - 389 (2010)
Chemical Equation Presented Radical changes: One single P-Rh-P angle determines whether the odd electron in the paramagnetic complex [Rh(trop2PPh)(PPh3)] is delocalized over the whole molecule (see picture, blue) or is localized on the P - Rh unit (red). The two energetically almost degenerate electromers exist in a fast equilibrium, and the red complex has the highest spin density at Rh of all low valent Rh complexes observed to date.
