1204403-47-3Relevant academic research and scientific papers
Catalytic intermolecular allyl-allyl cross-couplings between alcohols and boronates
Jimenez-Aquino, Agustin,Ferrer Flegeau, Emmanuel,Schneider, Uwe,Kobayashi, Shu
supporting information; experimental part, p. 9456 - 9458 (2011/10/02)
We developed catalytic intermolecular C(sp3)-C(sp3) cross-couplings between various allyl alcohols and allyl boronates, which proceeded smoothly in the presence of nickel(0) under mild conditions to form 1,5-dienes with excellent linear- and γ-selectivity; the use of boronates proved to be crucial in terms of reactivity.
Palladium(0) versus nickel(0) catalysis in selective functional- grouptolerant sp3-sp3 carbon-carbon bond formations
Flegeau, Emmanuel Ferrer,Schneider, Uwe,Kobayashi, Shue
experimental part, p. 12247 - 12254 (2010/06/11)
We have uncovered Pd°-catalyzed intermolecular nonsymmetrical Suzuki-Miyaura-type sp3-sp3 C-C bond formations between allyl carbonates and nontoxic allyl, allenyl, or propargyl boronates. This report represents the first use of these
