1204504-32-4

Basic information

• Product Name: (R)-N-(2,6-dibromophenyl)-N'-(1-phenylethyl)-formamidine
• Synonyms: (R)-N-(2,6-dibromophenyl)-N'-(1-phenylethyl)-formamidine
• CAS NO: 1204504-32-4
• Molecular Weight: 382.098
• Mol File: 1204504-32-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-N-(2,6-dibromophenyl)-N'-(1-phenylethyl)-formamidine(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-N-(2,6-dibromophenyl)-N'-(1-phenylethyl)-formamidine(1204504-32-4)
• EPA Substance Registry System: (R)-N-(2,6-dibromophenyl)-N'-(1-phenylethyl)-formamidine(1204504-32-4)

Safety Data

• Hazardous Substances Data: 1204504-32-4(Hazardous Substances Data)

Upstream product

• 608-30-0 2,6-dibromoaniline 
• 6948-01-2 (R)-(+)-α-methylbenzyl formamide 

Downstream Products

• 1204504-33-5 C₃₇H₄₀N₂Si₂ 

Relevant articles and documents

Double-stranded supramolecular assembly through salt bridge formation between rigid and flexible amidine and carboxylic acid strands

(Chemical Equation Presented) A series of monomeric strands consisting of m-terphenyl backbones with chiral rigid C-linked (3) and flexible N-linked (5) formamidines and achiral carboxylic acid (4) and flexible carboxymethyl (6) residues were synthesized, and their duplex formations through amidinium-carboxylate salt bridges were investigated by NMR, circular dichroism (CD), and UV-visible spectroscopies. The salt bridge-derived duplex formation was largely dependent on the structures of the formamidine and carboxylic acid strands, and the C-linked formamidine strand 3 formed a more stable duplex with the complementary carboxylic acid strands (4 and 6) than did the flexibleN-linked formamidine strand 5. The single crystal X-ray analysis revealed that the duplex 5·4 has a skewed right-handed double helical structure. A complementary duplex dimer was also synthesized from the dimers of 5 and 4 joined by diacetylene linkers. Variable-temperature CD measurements indicated that the duplex possesses a dynamic double helical structure resulting from the flexible N-linked formamidine units.