120467-66-5

Basic information

• Product Name: 1,1-bis(p-chlorophenyl)-2-ethoxycarbonyl-5-methylhexan-3-one
• CAS NO: 120467-66-5
• Molecular Weight: 407.337
• Mol File: 120467-66-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-bis(p-chlorophenyl)-2-ethoxycarbonyl-5-methylhexan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-bis(p-chlorophenyl)-2-ethoxycarbonyl-5-methylhexan-3-one(120467-66-5)
• EPA Substance Registry System: 1,1-bis(p-chlorophenyl)-2-ethoxycarbonyl-5-methylhexan-3-one(120467-66-5)

Safety Data

• Hazardous Substances Data: 120467-66-5(Hazardous Substances Data)

Upstream product

• 34036-16-3 5-methyl-3-oxo-hexanoic acid ethyl ester 
• 6306-46-3 1-[bromo(4-chlorophenyl)methyl]-4-chlorobenzene 
• 90-98-2 4,4'-Dichlorobenzophenone 
• 90-97-1 4,4'-dichlorobenzophenone 

Downstream Products

• 120467-67-6 1,1-bis(p-chlorophenyl)-5-methylhexan-3-one 

Relevant articles and documents

SYNTHESIS OF JUVABIONE ANALOGUES

Alkylation of various β-ketoesters IIIa-d with bis(p-methoxycarbonylphenyl)bromomethane (II) and bis(p-chlorophenyl)bromomethane (VI) followed by cleavage of ethoxycarbonyl group or hydrolysis and esterification gave methoxycarbonylphenyl and chlorophenyl analogues of ar-juvabione, respectively.Condensation of bis(p-methoxycarbonylphenyl)methanol (IX) with isovaleryl and trichloroacetyl chloride gave isovalerate X and trichloroacetate XI, respectively, while the condensation of bis(p-chlorophenyl)methanol (XII) with isovaleryl chloride and citronellyl bromide yieldedisovalerate XIII and citronellyl ether XIV, respectively.The methoxycarbonylation of aryl-alkyl ketones XVa-d with oxalyl chloride and treatment with methanol furnished various ar-juvabione analogues XVIa-d.The compounds Vb, Vc, Vd, XVIb, and XVIc showed high activity against Dysdercus koenigii at 1μg concentration.