1204754-02-8

Basic information

• Product Name: C₁₄H₂₀O₃
• Synonyms: C₁₄H₂₀O₃
• CAS NO: 1204754-02-8
• Molecular Weight: 236.311
• Mol File: 1204754-02-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: C₁₄H₂₀O₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₂₀O₃(1204754-02-8)
• EPA Substance Registry System: C₁₄H₂₀O₃(1204754-02-8)

Safety Data

• Hazardous Substances Data: 1204754-02-8(Hazardous Substances Data)

Upstream product

• 1446246-63-4 (4S)-2-(4-methoxyphenyl)-4-propyl-1,3-dioxane 
• 74-88-4 methyl iodide 
• 1204754-01-7 (S)-3-(4-methoxybenzyloxy)hexan-1-ol 

Downstream Products

• 1204754-03-9 C₁₇H₂₆O₃ 
• 1228294-02-7 C₁₈H₂₈O₃ 
• 1446246-61-2 ((4R,5R)-5-((S)-2-(4-methoxybenzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methanol 
• 1446246-62-3 (S,E)-5-(4-methoxybenzyloxy)oct-2-enylbenzoate 
• 1446246-64-5 (S,E)-5-(4-methoxybenzyloxy)oct-2-en-1-ol 
• 1446246-65-6 (2R,3R,5S)-2,3-dihydroxy-5-(4-methoxybenzyloxy)octyl benzoate 
• 1446246-66-7 {(4R,5R)-5-((S)-2-(4-methoxybenzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl}methyl benzoate 
• 1446246-67-8 (E)-4-((4R,5R)-5-((S)-2-(4-methoxybenzyloxy)pentyl)-2,2-dimethyl-1,3-dioxolan-4-yl)but-3-en-2-one 

Relevant articles and documents

Total synthesis of (6Z,9S)-3,4-trans-9-hydroxy-3-methyldodec-cis-6-en-4-olide and (6Z)-3,4-trans-9-oxo-3-methyldodec-cis-6-en-4-olide γ-butyrolactones

The first total synthesis of (6Z,9S)-3,4-trans-9-hydroxy-3-methyldodec-cis-6-en-4-olide and (6Z)-3,4-trans-9-oxo-3-methyldodec-cis-6-en-4-olide was achieved in a convergent pathway. The salient features of our synthesis include Ohira-Bestmann reaction, regioselective alkyne addition to terminal epoxide, TEMPO/BAIB mediated oxidative lactonization, and partial hydrogenation.

First stereoselective total synthesis of phomonol via oxa-Michael approach

Herein we report the first stereoselective total synthesis of phomonol via Sharpless asymmetric dihydroxylation and 6-exo-trig oxa-Michael addition as the key steps.