120490-00-8Relevant articles and documents
REACTION OF 1-CHLORO-1-METHYLCYCLOHEXANE WITH PHENYL- AND BENZYL- TRIMETHYLSILANES IN THE PRESENCE OF ALUMINIUM CHLORIDE
Bolestova, G. I.,Parnes, Z. N.,Vol'pin, M. E.
, p. 967 - 971 (2007/10/02)
In the reaction of 1-chloro-1-methylcyclohexane with phenyltrimethylsilane and benzyltrimethylsilane in the presence of aluminum chloride the chlorine atom is substituted by a phenyl or benzyl group with the formation of 1-methyl-1-phenyl- and 1-methyl-1-benzylcyclohexane, respectively.In the case of benzyltrimethylsilane the products from alkylation of the benzene ring of the benzyltrimethylsilane by the 1-methylcyclohexyl carbocation in the Friedel-Crafts reaction are formed in addition to 1-methyl-1-benzylcyclohexane.