120491-53-4Relevant academic research and scientific papers
TETRALITHIUM DERIVATIVES OF 1,4-DINITRO COMPOUNDS
Nekrasova, G. V.,Lipina, E. S.,Boldysh, E. E.,Perekalin, V. V.
, p. 1031 - 1035 (2007/10/02)
Double deprotonation at each reaction center in the dinitro compound 1,4-dinitrobutane and 1,4-dinitro-2-butane was investigated.On the basis of the structure of the bromination products it was shown that tetralithium derivatives are formed almost quantitatively in the first case and to a small degree in the second.The formation of the tetrabromide of dinitrobutane makes it possible to propose the halogenation reaction as a chemical method for the capture of the highly reactive products (intermediates) in double deprotonation.
