120544-15-2Relevant academic research and scientific papers
Mono- and bi-nuclear complexes of the rigid bidentate ligand 2-ethylthio-5-diphenylphosphinofuran
Bressan, Mario,Morvillo, Antonino,Brown, John M.
, p. 249 - 254 (2007/10/02)
The reactions of 2-ethylthio-5-diphenylphosphino-furan (TPF) with (or with under CO) have been shown to lead to trans or the cationic + species, (M = Rh, Ir), all with monodentate phosphorus-bound ligands.The latter gives rhodium-silver and rhodium-iridium heterobinuclear head-to-head 2+ and 2+ derivatives.A monomeric derivative with monodentate P-bound ligands has also benn prepared, and shown to react with to yield rhodium-gold heterobinuclear adducts as mixtures of head-to-head and head-t-tail isomers.
