120573-59-3Relevant academic research and scientific papers
CONJUGATED AZOALKENES, PART VI. α-OLEFINATED CARBONYL DERIVATIVES BY TREATMENT OF AZOALKENES WITH CARBOMETHOXYMETHYLENE TRIPHENYLPHOSPHORANE
Attanasi, Orazio A.,Filippone, Paolino,Santeusanio, Stefania
, p. 5787 - 5788 (2007/10/02)
α-Olefinated carbonyl derivatives have been obtained in good yield under very mild conditions by Wittig-type reaction of some conjugated azoalkenes with carbomethoxymethylene triphenylphosphorane.The reaction mechanism seems to implicate zwitterionic rather than cycloadduct intermediate, as usual for the Wittig reaction.
