120609-16-7Relevant articles and documents
Selective reduction of alkynes to Z-alkenes using hydrosilane functions immobilized on silica gel
Kini, Abhay D.,Nadkarni, Durgesh V.,Fry, James L.
, p. 1507 - 1510 (2007/10/02)
A solid reagent consisting of hydrosilane functions immobilized on the surface of silica gel was used in conjunction with acetic acid and tetrakis(triphenylphosphine)palladium(0) catalyst to effect the reduction of alkynes to Z-olefins. Simple filtration provides a convenient means for the reaction workup and isolation of products.
VINYLLITHIUMS FROM BUTYL VINYL TELLURIDES AND BIS-VINYL TELLURIDES
Barros, Simone M.,Comasseto, Joao V.,Berriel, Jorge
, p. 7353 - 7356 (2007/10/02)
Butyl vinyl tellurides and bis-vinyl tellurides furnish vinyllithiums with retention of configuration in good yields upon treatment with n-butyllithium at -78 deg C.
