120611-11-2Relevant academic research and scientific papers
C-phosphoniophosphaalkenes as precursors of Iσ4, 3σ2-diphosphaallenes: Scope and limitations
Martin, David,Gornitzka, Heinz,Baceiredo, Antoine,Bertrand, Guy
, p. 2619 - 2624 (2007/10/03)
The study of a general synthetic route to 1σ4, 3σ2-diphosphaallenes involving the reaction of LiHMDS with C-phosphoniophosphaalkenes is reported. The choice of the base is critical since the precursors are highly electrophilic species that react cleanly with methyl-, butyl-, mesityl-, or tert-butyllithium to afford C- phosphanylphosphonium ylides. The role of the substituents at the σ4-phosphorus centre has also been studied. The resulting phosphaallenes react cleanly with a Lewis acid and undergo [3+2] cycloaddition with azides to afford a five-membered heterocycle in a three-step process. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005.
Evidence for α-Phosphanyl-α'-sulfinylcarbene to α-Phosphoranyl-α'-sulfanylcarbene Rearrangement. Synthesis of 2-Oxo- and 2-Thioxo-1,2λ5-azaphosphetanes
Sicard, Ghislaine,Gruetzmacher, Hansjoerg,Baceiredo, Antoine,Ficher, Jean,Bertrand, Guy
, p. 4426 - 4430 (2007/10/02)
(trimethylsilyl)diazomethane (1) reacts with p-toluenesulfinyl chloride and p-toluenesulfonyl chloride, affording the same 2-oxo-1,2λ5-azaphosphetane 6 in 85 and 80percent yield, respectively.These results are r
