1206164-26-2Relevant academic research and scientific papers
Ni-Catalyzed Decarboxylative Cross-Coupling of Potassium Polyfluorobenzoates with Unactivated Phenol and Phenylmethanol Derivatives
Chen, Quan,Wu, Aizhen,Qin, Shengxiang,Zeng, Meiqi,Le, Zhiping,Yan, Zhaohua,Zhang, Hua
supporting information, p. 3239 - 3244 (2018/09/10)
A Ni-catalyzed decarboxylative cross-coupling of potassium polyfluorobenzoates with unactivated phenol and phenylmethanol derivatives is described. This novel transformation provides a practical and efficient protocol towards the synthesis of important polyfluorobiaryls and polyfluorinated diarylmethanes, and greatly enlarges the range of electrophiles utilized in decarboxylative coupling. Remarkably, preliminary mechanistic studies indicated the essential role of Zn(OAc)2 might lie in the enhancement of decarboxylation step. (Figure presented.).
Pd-catalyzed decarboxylative cross coupling of potassium polyfluorobenzoates with aryl bromides, chlorides, and triflates
Shang, Rui,Xu, Qing,Jiang, Yuan-Ye,Wang, Yan,Liu, Lei
supporting information; experimental part, p. 1000 - 1003 (2010/06/16)
Chemical Equetion Presentation Pd-catalyzed decarboxylative cross coupling of potassium polyfluorobenzoates with aryl bromides, chlorides, and triflates is achieved by using diglyme as the solvent. The reaction is useful for synthesis of polyfluorobiaryls
Copper-catalyzed decarboxylase cross-coupling of potassium polyfluorobenzoates with aryl iodides and bromides
Shang, Rui,Fu, Yao,Wang, Yan,Xu, Qing,Yu, Hai-Zhu,Liu, Lei
supporting information; experimental part, p. 9350 - 9354 (2010/03/04)
Chemical Equitation Presentation For copper only: The decarboxylative cross-coupling of readily accessible and nonvolatile potassium polyfluorobenzoates with aryl iodides and bromides using a copper catalyst provides poly-fluorobiaryls and polyfluorostilb
